Heat Transfer and Thermal Properties
Chapter 1 Translational Motion
🧭 Overview
🧠 One-sentence thesis
Heat transfer by conduction depends on material properties and geometry, while thermal expansion causes predictable dimensional changes that affect both individual objects and systems of objects made from the same material.
📌 Key points (3–5)
- Conduction rate factors: heat transfer by conduction is directly proportional to thermal conductivity, cross-sectional area, and temperature difference, but inversely proportional to length.
- Conduction vs radiation: infrared radiation transfers energy through electromagnetic waves (e.g., feeling warmth from a stove), while conduction transfers energy through molecular vibration without molecules traveling.
- Thermal expansion principle: objects expand when heated according to their coefficient of expansion; area expansion is approximately twice the linear expansion coefficient.
- Common confusion: in conduction, energy transfers but molecules don't travel from one end to the other; the mechanism is molecular vibration, not mass transport.
- Same-material systems: objects made of the same material expand at the same rate when heated together, maintaining their relative dimensional relationships.
🌡️ Heat transfer by conduction
🔢 The conduction formula
The rate of heat transfer through conduction follows this relationship:
- Rate = (thermal conductivity × cross-sectional area × temperature difference) / length
- Represented as: Q/t = (k × A × ΔT) / d
What increases conduction rate:
- Larger cross-sectional area (A)
- Greater temperature difference (ΔT)
- Higher thermal conductivity (k)
What decreases conduction rate:
- Greater length/thickness (d)
📐 Geometric effects
- Doubling area (A): increases the rate of transfer proportionally
- Doubling length (L): increases both the surface for energy absorption and the surface for energy dissipation
- Example: A door with 500 W heat transfer—making it thicker reduces the rate; making it larger or increasing the temperature difference increases the rate
⚠️ Common mistake
Don't confuse specific heat with thermal conductivity:
- Specific heat relates to energy storage capacity
- Thermal conductivity relates to energy transfer rate
- Only thermal conductivity appears in the conduction formula
🌊 Heat transfer mechanisms
📡 Infrared radiation
Infrared radiation: electromagnetic radiation that transfers energy without requiring physical contact or a medium.
- Not within the visible light range
- Example: feeling warmth when placing your hand near a warm stove—you are sensing infrared radiation
- Different mechanism from conduction
🥄 Molecular mechanism in conduction
Key distinction: Energy transfers, but molecules don't travel
- Energy moves through molecular vibration
- Molecules remain in place while passing energy to neighbors
- Example: A spoon in hot liquid—energy conducts from the hot end to the cool end, but the metal molecules don't migrate along the spoon
🔧 Thermal expansion
📏 Linear expansion
The change in length when an object is heated:
- Formula structure: change in length = (coefficient of linear expansion) × (original length) × (temperature change)
- Applies to one-dimensional changes
📐 Area expansion
The coefficient of area expansion for a material is approximately twice the coefficient of linear expansion.
- For a flat plate: change in area = (coefficient of area expansion) × (original area) × (temperature change)
- Example: A 0.1 m × 0.1 m plate (0.01 m² area) expands according to twice the linear coefficient
🔄 Same-material systems
Important principle: Objects made of the same material expand at the same rate
- They share the same coefficient of expansion
- All dimensions scale proportionally
- Example: A ball and ring made of the same material—if the ball fits through the ring at room temperature, it will still fit when both are heated together, because both the ball diameter and ring diameter increase by the same amount
🔬 Temperature-dependent properties
📊 Properties that increase with temperature
| Property | Behavior |
|---|---|
| Electrical resistance | Increases for most materials |
| Speed of sound in air | Increases |
| Gas volume (constant molecules) | Increases |
| Gas pressure (constant volume) | Increases (from PV = nRT) |
| Solid object length | Increases for most materials |
📉 Properties that decrease with temperature
- Gas density (when molecule count is constant): mass stays constant while volume increases, so density (mass/volume) decreases
⚙️ Work and ideal gases
🔄 Volume changes and work
Work done on an ideal gas: W = –PΔV (negative of pressure times change in volume)
Interpreting the sign:
- Compression (volume decreases): work is done on the gas
- Expansion (volume increases): work is done by the gas
- No volume change: no work is done
📍 Identifying work in process steps
- Steps with constant volume (no ΔV): zero work
- Steps with volume decrease: external force does work compressing the gas
- Steps with volume increase: gas does work expanding itself